Asymmetric Microbial Oxidation of Formaldehyde Dithioacetals
نویسندگان
چکیده
منابع مشابه
Formaldehyde degradation by catalytic oxidation.
Formaldehyde used for the disinfection of a laminar-flow biological safety cabinet was oxidatively degraded by using a catalyst. This technique reduced the formaldehyde concentration in the cabinet from about 5,000 to about 45 mg/m3 in 8 h. This technique should prove useful in other applications.
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We report herein on an accessible protocol for the asymmetric hydroformylation of vinylarenes using formaldehyde as a substitute for syngas. The regioselectivity (branched/linear = up to 96/4) and enantioselectivity (up to 95% ee) can be attributed to the use of chiral Ph-bpe as a ligand.
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ژورنال
عنوان ژورنال: Chemistry Letters
سال: 1986
ISSN: 0366-7022,1348-0715
DOI: 10.1246/cl.1986.2049